Hydrogen Production by Homogeneous Partial Oxidation of Propane

被引：13
|
作者：
Hognon, Celine [1 ]
Simon, Yves [1 ]
Marquaire, Paul-Marie [1 ]
机构：
[1] Nancy Univ, Lab React & Genie Proc, CNRS, ENSIC, F-54001 Nancy, France
来源：
ENERGY & FUELS | 2012年 / 26卷 / 03期
关键词：
JET-STIRRED REACTOR; LA2O3; CATALYST; METHANE; GAS; CONVERSION; MECHANISM; OLEFINS; DEHYDROGENATION; PYROLYSIS; KINETICS;
D O I：
10.1021/ef201938t
中图分类号：
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号：
0807 ; 0820 ;
摘要：
A kinetic study of the partial oxidation of propane was performed in a jet stirred reactor. The main goal of this study was to establish a detailed homogeneous mechanism of this reaction and explore the capability to produce H-2 and olefins. Various operating parameters are modified: temperature, residence time, and O-2/C3H8 ratio. The mechanism was validated by comparing experimental and simulated results. A different behavior was observed depending on the temperature. At 600 degrees C, the mechanism contains both an oxidation and a pyrolytic path. The main products are HD C2H4, CH4, CO, and O-2. At 800 degrees C, the mechanism mostly contains a pyrolytic path. The main products are H-2 and CO.
引用
收藏
页码：1496 / 1508
页数：13
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