Substituents effect on the electronic structure, spectra and photochemistry of [Ru(NH3)5(Py-X)]2+ complexes

被引：3
|
作者：
Sizova, OV [1 ]
Ivanova, N [1 ]
Sizov, VV [1 ]
Ershov, AY [1 ]
Baranovski, VI [1 ]
机构：
[1] St Petersburg State Univ, Fac Chem, St Petersburg 198504, Russia
来源：
INORGANICA CHIMICA ACTA | 2004年 / 357卷 / 02期
关键词：
ruthenium(II) complexes; metal to ligand charge transfer; dd-transitions; photochemistry;
D O I：
10.1016/j.ica.2003.06.008
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The diagrams of MLCT and d-d excited states of the complexes [Ru(NH3)(5)(py-X)](2+) are calculated using semiempirical CINDO/S method. Comparison of the relative energies of MLCT and d-d excited states leads to the understanding of the background of the rules, found earlier by Ford et al., that govern photochemical activity of the Ru(II) complexes under consideration. (C) 2003 Elsevier B.V. All rights reserved.
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页码：354 / 360
页数：7
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