Effect of Organics on Activity of Cu/ZSM-5 Catalyst for Selective Reduction of NO with NH3
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作者:
Suzuki, Kunio
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Natl Inst Adv Ind Sci & Technol, Res Ctr New Fuels & Vehicle Technol, Tsukuba, Ibaraki 3058565, JapanNatl Inst Adv Ind Sci & Technol, Res Ctr New Fuels & Vehicle Technol, Tsukuba, Ibaraki 3058565, Japan
Suzuki, Kunio
[1
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Haneda, Masaaki
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Nagoya Inst Technol, Ceram Res Lab, Gifu 5070071, JapanNatl Inst Adv Ind Sci & Technol, Res Ctr New Fuels & Vehicle Technol, Tsukuba, Ibaraki 3058565, Japan
Haneda, Masaaki
[2
]
Sasaki, Motoi
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Natl Inst Adv Ind Sci & Technol, Res Ctr New Fuels & Vehicle Technol, Tsukuba, Ibaraki 3058565, JapanNatl Inst Adv Ind Sci & Technol, Res Ctr New Fuels & Vehicle Technol, Tsukuba, Ibaraki 3058565, Japan
Sasaki, Motoi
[1
]
Hamada, Hideaki
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Natl Inst Adv Ind Sci & Technol, Res Ctr New Fuels & Vehicle Technol, Tsukuba, Ibaraki 3058565, JapanNatl Inst Adv Ind Sci & Technol, Res Ctr New Fuels & Vehicle Technol, Tsukuba, Ibaraki 3058565, Japan
Hamada, Hideaki
[1
]
机构:
[1] Natl Inst Adv Ind Sci & Technol, Res Ctr New Fuels & Vehicle Technol, Tsukuba, Ibaraki 3058565, Japan
[2] Nagoya Inst Technol, Ceram Res Lab, Gifu 5070071, Japan
The effect of co existing organics on the selective reduction of NO using ammonia as a reducing agent was investigated over Cu/ZSM-5 catalysts Addition of organics in the feed gas resulted in deactivation of the catalysts NH3-SCR activity at 200 degrees C decreased in the following order acetaldehyde>n decane>methyl decanoate, p-xylene>m-xylene After oxidation of the deactivated catalysts in an oxygen flow at 500 C, the activity of the catalyst was recovered Hence, the cause of the deactivation was considered to be a carbonaceous material deposited over the catalyst