Effect of Organics on Activity of Cu/ZSM-5 Catalyst for Selective Reduction of NO with NH3

被引:0
|
作者
Suzuki, Kunio [1 ]
Haneda, Masaaki [2 ]
Sasaki, Motoi [1 ]
Hamada, Hideaki [1 ]
机构
[1] Natl Inst Adv Ind Sci & Technol, Res Ctr New Fuels & Vehicle Technol, Tsukuba, Ibaraki 3058565, Japan
[2] Nagoya Inst Technol, Ceram Res Lab, Gifu 5070071, Japan
关键词
Nitrogen oxide; Selective catalytic reduction; Ammonia; Organics; Copper catalyst; ZSM-5; support; SCR;
D O I
10.1627/jpi.53.355
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
The effect of co existing organics on the selective reduction of NO using ammonia as a reducing agent was investigated over Cu/ZSM-5 catalysts Addition of organics in the feed gas resulted in deactivation of the catalysts NH3-SCR activity at 200 degrees C decreased in the following order acetaldehyde>n decane>methyl decanoate, p-xylene>m-xylene After oxidation of the deactivated catalysts in an oxygen flow at 500 C, the activity of the catalyst was recovered Hence, the cause of the deactivation was considered to be a carbonaceous material deposited over the catalyst
引用
收藏
页码:355 / 358
页数:4
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