Preparation of a mechanically interlocked polymer from a linear supramolecular polymer

被引：9
|
作者：
Zhang, Zibin [1 ]
Sun, Kechang [1 ]
Jin, Leqiong [1 ]
Xie, Chunsong [1 ]
Li, Shijun [1 ]
机构：
[1] Hangzhou Normal Univ, Coll Mat Chem & Chem Engn, Hangzhou 310036, Peoples R China
来源：
ORGANIC CHEMISTRY FRONTIERS | 2020年 / 7卷 / 12期
基金：
中国国家自然科学基金;
关键词：
GUEST MOLECULAR RECOGNITION; BETA-CYCLODEXTRIN; HOST; WATER; DRIVEN; MONOMERS; COMPLEXATION; NANOPARTICLES; COORDINATION; CHEMISTRY;
D O I：
10.1039/d0qo00315h
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A novel supramolecular polymer based on the pillar[5]arene/alkyl-1,2,3-triazole recognition motif and a suitable light responsive azobenzene stopper has been constructed. We found that the formation of the supramolecular polymer based ontrans-1is highly dependent on the monomer concentration. Moreover, by the irradiation of a high concentration solution oftrans-1at 365 nm, we successfully transformed this linear supramolecular polymer into a mechanically interlocked polymer composed ofcis-1by photoisomerization.
引用
收藏
页码：1453 / 1462
页数：10
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