In-Water Truly Monodisperse Aggregation of Gear-Shaped Amphiphiles Based on Hydrophobic Surface Engineering

被引：53

作者：

Hiraoka, Shuichi ^{[1
,2
]}

Nakamura, Takashi ^{[1
]}

Shiro, Motoo ^{[3
]}

Shionoya, Mitsuhiko ^{[1
]}

机构：

[1] Univ Tokyo, Grad Sch Sci, Dept Chem, Bunkyo Ku, Tokyo 1130033, Japan

[2] Japan Sci & Technol Agcy, Precursory Res Embryon Sci & Technol PRESTO, Kawaguchi, Saitama 3320012, Japan

[3] Rigaku Corp Ltd, Tokyo 1968666, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2010年 / 132卷 / 38期

关键词：

BUILDING-BLOCKS; ORGANIC CAPSULE; DOUBLE HELIX; OLIGORESORCINOLS; MOLECULES; ARCHITECTURES; MEMBRANES; NANOTUBE;

D O I：

10.1021/ja1069135

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Exactly six gear-shaped amphiphiles self-assemble into a highly stable, water-soluble, box-shaped capsule, in which indented hydrophobic surfaces of the components mesh with each other like gears. A water-soluble, tetrahedron-shaped capsule was also constructed from four gear-shaped amphiphiles with a template guest. These findings provide a guideline for creating aggregates with a given number of amphiphiles based on hydrophobic surface engineering.

引用

页码：13223 / 13225

页数：3