Structures of bimetallic assemblies derived from a macrocyclic dinuclear copper(II) complex and [Cr(ox)3]3- or [Co(CN)6]3-

被引：11
|
作者：
Miyazato, Y
Ohba, M
Okawa, H
机构：
[1] Kyushu Univ, Fac Sci, Dept Chem, Higashi Ku, Fukuoka 8128581, Japan
[2] Kyoto Univ, Grad Sch Engn, Dept Synth Chem & Biol Chem, Nishikyo Ku, Kyoto 6158510, Japan
来源：
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2005年 / 78卷 / 09期
关键词：
D O I：
10.1246/bcsj.78.1646
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A dinuclear copper(II) complex, [Cu-2(L)](ClO4)(2), of the macrocyclic ligand (H2L) derived from the [2:2] condensation of 2,6-diformyl-4-methylphenol and 1,3-diaminopropane, was reacted with [Cr(ox)(3)](3-) and [Co(CN)(6)](3-) to produce [Cu-2(L)](3)[Cr(ox)(3)](2)center dot 6MeOH (1) of a discrete octanuclear structure and [Cu-2(L)](3)[Co(CN)(6)](2)center dot 6MeOH center dot 2DMF (2) of a 2-D grid structure, respectively.
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页码：1646 / 1648
页数：3
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