Tetraaqua(2,2′-bipyridine)zinc(II) terephthalate

被引：10
|
作者：
Xu, HB
Liang, YC
Su, ZM [1 ]
Zhao, YH
Shao, KZ
Zhang, HJ
Yue, SM
机构：
[1] NE Normal Univ, Fac Chem, Inst Funct Mat Chem, Changchun 130024, Jilin, Peoples R China
[2] Tech Univ Munich, Inst Anorgan Chem, D-85747 Garching, Germany
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2004年 / 60卷
关键词：
D O I：
10.1107/S1600536803029210
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
A discrete zinc(II) coordination complex, [Zn(bpy)(H2O)(4)](tp) [bpy = 2,2'-bipyridine (C10H8N2) and tp = terephthalate (C8H4O4)], has been prepared from the hydrothermal reaction of Zn(CH3COO)(2).2H(2)O, bpy and terephthalic acid in water. The zinc ion has a distorted octahedral coordination environment, with two N atoms from bpy and four water molecules. The terephthalate anion does not coordinate to the Zn-II metal center. Hydrogen bonds and pi-pi stacking interactions play important roles in the production of a three-dimensional supramolecular structure.
引用
收藏
页码：M142 / M144
页数：3
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