Aminobisphosphonate Polymers via RAFT and a Multicomponent Kabachnik-Fields Reaction

被引：40

作者：

Bachler, Patricia R. ^{[1
]}

Schulz, Michael D. ^{[1
]}

Sparks, Chelsea A. ^{[1
]}

Wagener, Kenneth B. ^{[1
]}

Sumerlin, Brent S. ^{[1
]}

机构：

[1] Univ Florida, Dept Chem, George & Josephine Butler Polymer Res Lab, Ctr Macromol Sci & Engn, Gainesville, FL 32611 USA

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2015年 / 36卷 / 09期

基金：

美国国家科学基金会;

关键词：

aminobisphosphonate; Kabachnik-Fields; Moedritzer-Irani; multicomponent reactions; postpolymerization reactions; reversible addition-fragmentation chain transfer; PHOSPHORUS-CONTAINING POLYMERS; ONE-POT SYNTHESIS; IN-VITRO; RADICAL POLYMERIZATION; BISPHOSPHONATES; CHEMISTRY; POLYPHOSPHATES; OPPORTUNITY; POLYAMIDES; COPOLYMERS;

D O I：

10.1002/marc.201500060

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Polyacrylamides containing pendant aminobisphosphonate groups are synthesized via reversible addition-fragmentation chain transfer (RAFT) polymerization and a multicomponent postpolymerization functionalization reaction. A Moedritzer-Irani reaction installs the phosphonic acid groups on well-defined, RAFT-generated polymers bearing a pendant amine. An alternate route to the same materials is developed utilizing a three-component Kabachnik-Fields reaction and subsequent dealkylation. Kinetics of the RAFT polymerization of the polymer precursor are studied. Successful functionalization is demonstrated by NMR and FTIR spectroscopy and elemental analysis of the final polymers.

引用

页码：828 / 833

页数：6

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