Melt Rheological and Thermoresponsive Shape Memory Properties of HDPE/PA6/POE-g-MAH Blends

被引:14
|
作者
Li, Shu-Cai [1 ]
Tao, Lei [1 ]
机构
[1] Tianjin Univ Sci & Technol, Coll Mat Sci & Chem Engn, Tianjin 300457, Peoples R China
关键词
Blend; Compatibilization; High density polyethylene; Nylon6; Rheology; Thermoresponsive shape memory; RUBBER;
D O I
10.1080/03602550903147320
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
High density polyethylene (HDPE)/nylon6 (PA6) blends were prepared by means of melt extrusion and using ethylene - octane copolymer graft maleic anhydride (POE-g-MAH) as a reactive compatibilizer. Phase morphology, rheological and thermoresponsive shape memory properties of the blends had been studied. The results showed that addition of POE-g-MAH could increase compatibility and phase-interfacial adhesion between HDPE and PA6, decrease the temperature sensitivity of the melt, improve the shape memory property and processability of HDPE/PA6 blends. The shape recovery rate of HDPE/PA6/POE-g-MAH (80/20/10) blend is 96.5% when the stretch ratio is 75% and optimal shape recovery response temperature is 135 degrees C.
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页码:218 / 222
页数:5
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