Synthesis of α-Amino Phosphonates from One-Pot Three-Component Condensation Catalyzed by Bamboo Char Sulfonic Acid

被引：5
|
作者：
Zhou, Xiaohong [1 ]
Xu, Qiong [1 ]
Liang, Jing [1 ]
Fu, Zaihui [1 ]
Yin, Dulin [1 ]
机构：
[1] Hunan Normal Univ, Inst Fine Catalysis & Synth, Hunan Engn Lab Petrochem New Mat, Key Lab Resource Fine Proc & Adv Mat,Univ Hunan P, Changsha 410081, Hunan, Peoples R China
来源：
CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2012年 / 32卷 / 02期
基金：
中国国家自然科学基金;
关键词：
bamboo char sulfonic acid; heterogeneous catalysis; one-pot reaction; alpha-amino phosphonates; ENANTIOSELECTIVE HYDROPHOSPHONYLATION; ASYMMETRIC-SYNTHESIS; LANTHANIDE TRIFLATE; REACTIVITY; IMINES; ACCESS;
D O I：
10.6023/cjoc1012142
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
By using fresh bamboo condensation raw material, bamboo char sulfonic acid was obtained via sulfuric acid charring and sulfonation, which catalyzed the one-pot three-component synthesis of alpha-amino phosphonates by condensation of various aromatic aldehydes with aromatic amines and diethyl phosphite. Experimental results have shown that bamboo char sulfonic acids have advantages of high activity, simplicity of operation, wide range of sources and easy recycle.
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收藏
页码：393 / 396
页数：4
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