Brass and Bronze as Effective CO2 Reduction Electrocatalysts

被引：46

作者：

He, Jingfu ^{[1
]}

Dettelbach, Kevan E. ^{[1
]}

Huang, Aoxue ^{[1
]}

Berlinguette, Curtis P. ^{[1
,2
,3
]}

机构：

[1] Univ British Columbia, Dept Chem, 2036 Main Mall, Vancouver, BC V6T 1Z1, Canada

[2] Univ British Columbia, Dept Chem & Biol Engn, 2360 East Mall, Vancouver, BC V6T 1Z3, Canada

[3] Univ British Columbia, Stewart Blusson Quantum Matter Inst, 2355 East Mall, Vancouver, BC V6T 1Z4, Canada

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2017年 / 56卷 / 52期

关键词：

brass; bronze; CO evolution; CO2; reduction; HCOOH evolution; CARBON-DIOXIDE; ELECTROCHEMICAL REDUCTION; AQUEOUS CO2; ELECTROREDUCTION; CATALYSTS;

D O I：

10.1002/anie.201709932

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Electrochemically reducing CO2 into fuels using renewable electricity is a contemporary global challenge that requires significant advances in catalyst design. Photodeposition techniques were used to screen ternary alloys of Cu-Zn-Sn, which includes brass and bronze, for the electrocatalytic reduction of CO2 to CO and formate. This analysis identified Cu0.2Zn0.4Sn0.4 and Cu0.2Sn0.8 to be capable of reaching Faradaic efficiencies of >80% for CO and formate formation, respectively, and capable of achieving partial current densities of 3 mA cm(-2) at an overpotential of merely 200 mV.

引用

页码：16579 / 16582

页数：4

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