Cp*Co(III)-catalyzed direct functionalization of aromatic C-H bonds with α-diazomalonates

被引：86

作者：

Liu, Xu-Ge ^{[1
]}

Zhang, Shang-Shi ^{[1
]}

Wu, Jia-Qiang ^{[1
]}

Li, Qingjiang ^{[1
]}

Wang, Honggen ^{[1
]}

机构：

[1] Sun Yat Sen Univ, Sch Pharmaceut Sci, Guangzhou 510006, Guangdong, Peoples R China

来源：

TETRAHEDRON LETTERS | 2015年 / 56卷 / 27期

基金：

中国国家自然科学基金;

关键词：

Cobalt; C-H activation; Carbenes; C-C coupling; CATALYZED DIRECT ALKYLATION; N-TOSYLHYDRAZONES; DIAZO-COMPOUNDS; C(SP(2))-H; ARENES; ACTIVATION; CYANATION; ALKENYLATION; CONSTRUCTION; ALKYNYLATION;

D O I：

10.1016/j.tetlet.2015.05.025

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Cp*Co(III)-catalyzed intermolecular C(sp(2))-C(sp(3)) assembly of (hetero)arenes with alpha-diazomalonates using a direct C-H functionalization logic was developed. A series of (hetero)arenes underwent alkylation efficiently under the assistance of pyrazolyl and pyrimidyl directing groups under relatively mild and operationally simple reaction conditions. Good functional group tolerance, satisfactory yields, and excellent regioselectivity were found. (C) 2015 Elsevier Ltd. All rights reserved.

引用

页码：4093 / 4095

页数：3

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