Porous nitrogen-doped carbon/MnO coaxial nanotubes as an efficient sulfur host for lithium sulfur batteries

被引：39
|
作者：
Lin, Chao [1 ]
Qu, Longbing [2 ]
Li, Jiantao [1 ]
Cai, Zhengyang [1 ]
Liu, Haoyun [1 ]
He, Pan [1 ]
Xu, Xu [1 ]
Mai, Liqiang [1 ]
机构：
[1] Wuhan Univ Technol, State Key Lab Adv Technol Mat Synth & Proc, Luoshi Rd 122, Wuhan 430070, Hubei, Peoples R China
[2] Univ Melbourne, Dept Mech Engn, Melbourne, Vic 3010, Australia
来源：
NANO RESEARCH | 2019年 / 12卷 / 01期
基金：
中国国家自然科学基金;
关键词：
nitrogen doping; porous; MnO; carbon nanotubes; sulfur batteries; HIGH-PERFORMANCE; POLYSULFIDE MEDIATOR; GRAPHENE; COMPOSITE; CATHODE; NANOSHEETS; NANOCAGES;
D O I：
10.1007/s12274-018-2203-9
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
As a promising candidate for next generation energy storage devices, lithium sulfur (Li-S) batteries still confront rapid capacity degradation and low rate capability. Herein, we report a well-architected porous nitrogen-doped carbon/MnO coaxial nanotubes (MnO@PNC) as an efficient sulfur host material. The host shows excellent electron conductivity, sufficient ion transport channels and strong adsorption capability for the polysulfides, resulting from the abundant nitrogen-doped sites and pores as well as MnO in the carbon shell of MnO@PNC. The MnO@PNC-S composite electrode with a sulfur content of 75 wt.% deliveries a specific capacity of 802 mAhg(-1) at a high rate of 5.0 C and outstanding cycling stability with a capacity retention of 82% after 520 cycles at 1.0 C.
引用
收藏
页码：205 / 210
页数：6
相关论文
共 50 条
  • [1] Porous nitrogen-doped carbon/MnO coaxial nanotubes as an efficient sulfur host for lithium sulfur batteries
    Chao Lin
    Longbing Qu
    Jiantao Li
    Zhengyang Cai
    Haoyun Liu
    Pan He
    Xu Xu
    Liqiang Mai
    [J]. Nano Research, 2019, 12 : 205 - 210
  • [2] Biomass-derived nitrogen-doped hierarchical porous carbon as efficient sulfur host for lithium–sulfur batteries
    Qinghuiqiang Xiao
    Gaoran Li
    Minjie Li
    Ruiping Liu
    Haibo Li
    Pengfei Ren
    Yue Dong
    Ming Feng
    Zhongwei Chen
    [J]. Journal of Energy Chemistry, 2020, 44 (05) : 61 - 67
  • [3] Biomass-derived nitrogen-doped hierarchical porous carbon as efficient sulfur host for lithium-sulfur batteries
    Xiao, Qinghuiqiang
    Li, Gaoran
    Li, Minjie
    Liu, Ruiping
    Li, Haibo
    Ren, Pengfei
    Dong, Yue
    Feng, Ming
    Chen, Zhongwei
    [J]. JOURNAL OF ENERGY CHEMISTRY, 2020, 44 : 61 - 67
  • [4] Hierarchically porous nitrogen-doped carbon as cathode for lithium–sulfur batteries
    Rui Wu
    Siguo Chen
    Jianghai Deng
    Xun Huang
    Yujie Song
    Ruiyi Gan
    Xiaoju Wan
    Zidong Wei
    [J]. Journal of Energy Chemistry, 2018, (06) : 1661 - 1667
  • [5] Hierarchically porous nitrogen-doped carbon as cathode for lithium–sulfur batteries
    Rui Wu
    Siguo Chen
    Jianghai Deng
    Xun Huang
    Yujie Song
    Ruiyi Gan
    Xiaoju Wan
    Zidong Wei
    [J]. Journal of Energy Chemistry, 2018, 27 (06) : 1661 - 1667
  • [6] Nitrogen-doped carbon nanotubes intertwined with porous carbon with enhanced cathode performance in lithium-sulfur batteries
    Long, Tao
    Meng, Fancheng
    Xu, Bin
    Zhao, Yixin
    Liu, Weilin
    Wei, Xiangfeng
    Zheng, Lianxi
    Liu, Jiehua
    [J]. SUSTAINABLE ENERGY & FUELS, 2020, 4 (08) : 3926 - 3933
  • [7] Nitrogen-doped porous graphene/MnO2 composite as sulfur hosts for lithium-sulfur batteries
    Yu, Xiangtao
    Zhu, Xiaoming
    Pei, Ziyuan
    Li, Yongpeng
    Li, Chenwei
    Sui, Zhuyin
    [J]. DIAMOND AND RELATED MATERIALS, 2021, 118
  • [8] Hierarchically porous nitrogen-doped carbon as cathode for lithium-sulfur batteries
    Wu, Rui
    Chen, Siguo
    Deng, Jianghai
    Huang, Xun
    Song, Yujie
    Gan, Ruiyi
    Wan, Xiaoju
    Wei, Zidong
    [J]. JOURNAL OF ENERGY CHEMISTRY, 2018, 27 (06) : 1661 - 1667
  • [9] Facile preparation of nitrogen-doped hierarchical porous carbon as a sulfur cathode host for high performance lithium-sulfur batteries
    Liu, Lei
    Yang, Feng
    Ge, Lei
    Liu, Chenhao
    Wang, Hao
    Cui, Lishan
    Yang, Hong
    [J]. MICROPOROUS AND MESOPOROUS MATERIALS, 2021, 312
  • [10] Nitrogen and sulfur co-doped hierarchical porous carbon as functional sulfur host for lithium-sulfur batteries
    Wang, Biao
    Hu, Jinlong
    Zhang, Lingzhi
    [J]. Materials Today Communications, 2021, 27
12345