Alternating copolymerization of ethylene and 5-hexen-1-ol with [ethylene(1-indenyl)(9-fluorenyl)]-zirconium dichloride/methylaluminoxane as the catalyst

被引：1
|
作者：
Hagihara, H
Murata, M
Uozumi, T
机构：
[1] Natl Inst Mat & Chem Res, Dept Polymer Chem, Tsukuba, Ibaraki 3058565, Japan
[2] Japan Chem Innovat Inst, Joint Res Ctr Precis Polymerizat, Tsukuba, Ibaraki 3058565, Japan
[3] Japan Adv Inst Sci & Technol, Sch Mat Sci, Tatsunokuchi, Ishikawa 9231292, Japan
来源：
MACROMOLECULAR RAPID COMMUNICATIONS | 2001年 / 22卷 / 05期
关键词：
D O I：
10.1002/1521-3927(20010301)22:5<353::AID-MARC353>3.0.CO;2-G
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The copolymerization of ethylene and 5-hexen-1-ol pretreated with trimethylaluminium was performed using [ethylene(1-indenyl)(9-fluorenyl)]zirconium dichloride/methylaluminoxane as the catalyst. The 5-hexen-1-ol unit in the copolymer could be increased to about 50-mol-% with increasing [5-hexen-1-ol/ethylene] ratio. C-13 NMR analysis proved that the poly(ethylene-co-(5-hexen-1-ol)) containing 50-mol-% of 5-hexen-1-ol units is an almost alternating copolymer.
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页码：353 / 357
页数：5
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