Visible-light-driven metal-free aerobic synthesis of highly diastereoselective phosphinoylpyrroloindoles

被引：27
|
作者：
Gorre, Ramesh [1 ,2 ]
Enagandhula, Damodar [1 ]
Balasubramanian, Sridhar [2 ,3 ]
Akondi, Srirama Murthy [1 ,2 ]
机构：
[1] CSIR Indian Inst Chem Technol CSIR IICT, Dept Organ Synth & Proc Chem, Hyderabad 500007, India
[2] Acad Sci & Innovat Res AcSIR, Ghaziabad 201002, India
[3] CSIR IICT, Dept Analyt Chem, Hyderabad 500007, India
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2020年 / 18卷 / 07期
关键词：
PHOSPHINE OXIDES; ARYL; CYCLIZATION; INDOLE;
D O I：
10.1039/c9ob02730k
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A visible-light-driven metal-free phosphorus radical mediated construction of 2-phosphinoyl-3H-pyrrolo[1,2,a]indoles is described. This mild tandem phosphinoylation/cyclization protocol utilizes air as a green oxidant and proceeds in a short span of time at room temperature with high functional group tolerance, and excellent chemo- and diastereoselectivity.
引用
收藏
页码：1354 / 1358
页数：5
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