Oxidative and nonoxidative conversion of C2 hydrocarbons on ZSM-5

被引：2
|
作者：
Vereshchagin, SN
Shishkina, NN
Anshits, AG
机构：
[1] Inst Chem Nat Organ Mat, Krasnoyarsk 660036, Russia
[2] Krasnoyarsk State Tech Univ, Dept Chem, Krasnoyarsk 660074, Russia
来源：
CATALYSIS TODAY | 1998年 / 42卷 / 03期
基金：
俄罗斯基础研究基金会;
关键词：
ZSM-5; ethylene; oxidative conversion;
D O I：
10.1016/S0920-5861(98)00106-0
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Reaction of C-1-C-2 hydrocarbon conversion on decationated HNaZSM-5 at 50-400 degrees C under nonoxidative and oxidative conditions is described. Experimental data which show the influence of population density of active surface centres on the course of the reaction are presented. Possible cooperative action of isolated acid centres and participation of radical intermediates in oxidative conversion are discussed. (C) 1998 Elsevier Science B.V. AU rights reserved.
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页码：303 / 310
页数：8
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