Metal-Organic Framework Regioisomers Based on Bifunctional Ligands

被引：54
|
作者：
Kim, Min [1 ]
Boissonnault, Jake A. [1 ]
Phuong V. Dau [1 ]
Cohen, Seth M. [1 ]
机构：
[1] Univ Calif San Diego, Dept Chem & Biochem, La Jolla, CA 92093 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 51期
基金：
美国国家科学基金会;
关键词：
bifunctional MOFs; framework flexibility; metal-organic frameworks; porous solids; regioisomers; N-BROMOSUCCINIMIDE;
D O I：
10.1002/anie.201106429
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Regioisomeric MOFs: A series of bifunctional metal-organic framework (MOF) regioisomers has been produced from amino-halo benzene dicarboxylate (NH 2X-BDC) ligands. Zr IV- and Zn II-based MOFs were synthesized and for the flexbile Zn II-based MOFs, gas sorption properties were dependent on the ligand substitution pattern. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：12193 / 12196
页数：4
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