Temperature-Dependent Change of Extraction Performance of Soft Cadmium(II) Ion with TPEN-NIPA Gel. Studies on the Effect of the Ethylenediamine Skeleton

被引：6

作者：

Maekawa, Tetsuya ^{[1
]}

Kida, Tatsuya ^{[1
]}

Miyazaki, Yuji ^{[1
]}

Watanabe, Wataru ^{[1
]}

Inaba, Yusuke ^{[2
]}

Takeshita, Kenji ^{[2
]}

Mori, Atsunori ^{[1
]}

机构：

[1] Kobe Univ, Dept Chem Sci & Engn, Nada Ku, Kobe, Hyogo 6578501, Japan

[2] Tokyo Inst Technol, Integrated Res Inst, Yokohama, Kanagawa 2268503, Japan

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2011年 / 84卷 / 01期

关键词：

NITROGEN-DONOR LIGAND; ENCAPSULATING HEXADENTATE-LIGAND; HETEROCYCLIC N-DONORS; SEPARATION; ACID; COMPLEXATION; SELECTIVITY; LANTHANIDE; BEHAVIOR; AM(III);

D O I：

10.1246/bcsj.20100151

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

TPEN (N,N,N',N'-tetrakis(2-pyridylmethyl)ethylenediamine) derivatives of different skeleton of the ethylene moiety are designed and synthesized. The obtained product is subjected to radical copolymerization with N-isopropylacrylamide (NIPA) to afford the polymer gel. Temperature-dependent extraction performance of TPEN derivatives and the corresponding polymer gels is compared at different temperatures and pH values.

引用

页码：122 / 124

页数：3

共 3 条

[1] Thermo-responsive extraction of cadmium(II) ion with TPEN-NIPA gel. Effect of the number of polymerizable double bond toward gel formation and the extracting behavior
Fukuoka, Sachio
Kida, Tatsuya
Nakajima, Yasutaka
Tsumagari, Takayuki
Watanabe, Wataru
Inaba, Yusuku
Mori, Atsunori
Matsumura, Tatsuro
Nakano, Yoshio
Takeshita, Kenji
TETRAHEDRON, 2010, 66 (09) : 1721 - 1727
[2] Thermoresponsive extraction of cadmium(II) ions by poly(TPEN-NIPA) gels. Effect of chain length and branched spacer structure on gel formation and extraction behavior
Inaba, Yusuke
Tsumagari, Takayuki
Kida, Tatsuya
Watanabe, Wataru
Nakajima, Yasutaka
Fukuoka, Sachio
Mori, Atsunori
Matsumura, Tatsuro
Nakano, Yoshio
Takeshita, Kenji
POLYMER JOURNAL, 2011, 43 (07) : 630 - 634
[3] Thermoresponsive extraction of cadmium(II) ions by poly(TPEN–NIPA) gels. Effect of chain length and branched spacer structure on gel formation and extraction behavior
Yusuke Inaba
Takayuki Tsumagari
Tatsuya Kida
Wataru Watanabe
Yasutaka Nakajima
Sachio Fukuoka
Atsunori Mori
Tatsuro Matsumura
Yoshio Nakano
Kenji Takeshita
Polymer Journal, 2011, 43 : 630 - 634

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