Enhancement of structural and magnetic properties of M-type hexaferrite permanent magnet based on synthesis temperature

The main purpose of this research work is to develop the single domain magnetic particles of M-type barium hexaferrite (BaFe12O19) using oxide precursors employing conventional powder metallurgy technique. The phase formation and magnetic performance of the powders and magnets will be optimized by adjusting calcination and sintering temperatures. The synthesis of M-type barium hexaferrite was carried out in two sections. A series of four samples have been prepared by initial wet mixed powders calcined at different temperatures, i.e., 750, 850, 950 and 1050 degrees C. On the basis of structural analysis, the sample calcined at 950 degrees C has been selected and further divided into four parts to sintered them at 1100,1150,1200 and 1250 degrees C. The structural measurements depict the confirmation of M-type barium hexaferrite structure. SEM micrographs show the hexagonal-shaped grains. The abrupt decrease in coercivity for the sample sintered at 1250 degrees C has been seen which may be due to high sintering temperature, at which the particles have multi-domain properties.