Template-directed synthesis of aragonite under supramolecular hydrogen-bonded Langmuir monolayers

被引：161
|
作者：
Litvin, AL
Valiyaveettil, S
Kaplan, DL
Mann, S
机构：
[1] GEOCENTERS INC,NATICK,MA 01760
[2] TUFTS UNIV,CTR BIOTECHNOL,MEDFORD,MA 02155
[3] MAX PLANCK INST POLYMER RES,D-55128 MAINZ,GERMANY
[4] UNIV BATH,SCH CHEM,BATH BA2 7AY,AVON,ENGLAND
来源：
ADVANCED MATERIALS | 1997年 / 9卷 / 02期
关键词：
D O I：
10.1002/adma.19970090205
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The design of supramolecular templates to direct the synthesis of organized inorganic materials is illustrated for aragonite (CaCO3), which is metastable under ambient conditions but found in gall-stones, fish otoliths, etc. Spreading of the template 5-hexadecyloxyisophthalic acid at the air/water interface is shown to result in the specific nucleation of aragonite from supersaturated calcium bicarbonate solution without additives.
引用
收藏
页码：124 / 127
页数：4
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