Densities and Viscosities for Binary Mixtures of the Ionic Liquid N-Ethyl Piperazinium Propionate with n-Alcohols at Several Temperatures

被引:19
|
作者
Shao, Dongbei [1 ]
Lu, Xiaoxing [1 ]
Fang, Wenjun [1 ]
Guo, Yongsheng [1 ]
Xu, Li [1 ]
机构
[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Zhejiang, Peoples R China
来源
基金
中国国家自然科学基金;
关键词
METHANOL; ETHANOL; SOLUBILITY; DEPENDENCE;
D O I
10.1021/je201116t
中图分类号
O414.1 [热力学];
学科分类号
摘要
A novel ionic liquid N-ethyl piperazinium propionate, [NEPP], was prepared, and the densities viscosities for binary mixtures of [NEPP] with methanol, ethanol, n-propanol, and n-butanol were measured over the whole concentration range at (298.15, 303.15, 308.15, and 313.15) K and 0.1 MPa. The data of the excess molar volume, V-m(E), were calculated and fitted with the Redlich-Kister type polynomial equation. The values of V-m(E) of the investigated systems are all negative, indicating that the ion-dipole interactions play important roles between the molecules of the ionic liquid and the alcohols.
引用
收藏
页码:937 / 942
页数:6
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