Low temperature magnetic properties of layered compounds:: NaLnTiO4 (Ln = Sm, Eu, Gd, Tb, Dy, Ho and Er)

被引:10
|
作者
Ozawa, T. C. [1 ]
Ikoshi, A. [2 ]
Taniguchi, T. [2 ]
Mizusaki, S. [2 ]
Nagata, Y. [2 ]
Noro, Y. [3 ]
Samata, H. [4 ]
机构
[1] Natl Inst Mat Sci, Tsukuba, Ibaraki 3050044, Japan
[2] Aoyama Gakuin Univ, Coll Sci & Engn, Kanagawa 1578572, Japan
[3] Kawazoe Frontier Technol Co Ltd, Kanagawa 931113, Japan
[4] Kobe Univ, Fac Maritime Sci, Higashinada Ku, Kobe, Hyogo 6580022, Japan
关键词
larahanide magnetism; layered oxide; weak ferromagnetism; Ruddlesden-Popper phase;
D O I
10.1016/j.jallcom.2006.10.055
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A series orthorhombic NaLnTiO(4) (Ln=lanthanides) has been synthesized and characterized. These compounds all crystallize in A-site ordered n=1 Ruddlesden-Popper phase (A(n+1)B(n)O(3n+1)) Structure. The weak ferromagnetism with large magnetization has been observed for Ln = Tb and Dy, and non-linear field dependence of magnetization without hysteresis has been observed for Ln = Er and Ho. By performing the symmetry operations, two possible canted spin arrangements have been proposed. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:38 / 43
页数:6
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