The electrochemical response of microperoxidase in non-aqueous solvents

被引：3
|
作者：
O'Donoghue, David [1 ]
Magner, Edmond [1 ]
机构：
[1] Univ Limerick, Mat & Surface Sci Inst, Dept Chem & Environm Sci, Limerick, Ireland
来源：
ELECTROCHIMICA ACTA | 2007年 / 53卷 / 03期
关键词：
microperoxidase-11; non-aqueous electrochemistry;
D O I：
10.1016/j.electacta.2007.04.117
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
Microperoxidase-11 (MP-11) was immobilised at gold electrodes and characterised using UV-vis and resonance Raman spectroscopy. On immersion in a range of non-aqueous solvents, no significant spectroscopic changes were observed. The redox potential of MP-11 was determined in 16 solvents and ranged from -384 to -228 mV. The redox potential was independent of the dielectric constant and hydrophobicity of the solvents examined. (c) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码：1134 / 1139
页数：6
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