Au and Pt nanoparticles supported on Ni promoted MoS2 as efficient catalysts for p-nitrophenol reduction

被引:36
|
作者
Akbarzadeh, Elham [1 ]
Bahrami, Farnaz [1 ]
Gholami, Mohammad Reza [1 ]
机构
[1] Sharif Univ Technol, Dept Chem, Tehran 1136511155, Iran
基金
美国国家科学基金会;
关键词
P-nitrophenol; Catalytic reduction; Ni promoted MoS2; Noble metal nanoparticles; METAL-ORGANIC FRAMEWORK; IN-SITU GROWTH; BIMETALLIC NANOPARTICLES; NANOSHEETS; HYDROGEN; AG; NANOSTRUCTURES; NANOCOMPOSITES; INTERFACES; ALLOY;
D O I
10.1016/j.jwpe.2020.101142
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
In present study, an efficient method was used to synthesis Au and Pt nanoparticles on Ni modified MoS2 (MNi/MoS2 (M = Au and Pt). The morphology and structure of the prepared products were characterized using different microscopic and spectroscopic methods. The as-synthesized MNi/MoS2 nanocomposites were applied for catalytic reduction of p-nitrophenol (P-NP) in the presence of NaBH4. P-NP is one of the prevalent contaminants in wastewaters, while its corresponding aromatic amine (4-aminophenol) is a precious intermediate for manufacturing of important materials such as pharmaceuticals. The obtained catalytic results indicated that noble metal nanoparticles significantly affect catalytic performance of MoS2. Synergistic effect between metal nanoparticles and MoS2 was introduced as the origin of this improved catalytic activity of metals decorated MoS2 particles. The enhanced catalytic activity of Ni modified MoS2 particles in comparison to that of unmodified MoS2 nanocomposites emphasis on the role of Ni in catalytic efficiency.
引用
收藏
页数:9
相关论文
共 50 条
  • [1] Gold nanoparticles supported on titania for the reduction of p-nitrophenol
    Yazid, Hanani
    Adnan, Rohana
    Farrukh, Muhammad Akhyar
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 2013, 52 (02): : 184 - 191
  • [2] Catalytic activity of Au, Ni and Au/Ni nanostructures in the reduction of p-nitrophenol
    Bankert, Laura
    Mbindyo, Jeremiah
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2016, 251
  • [3] Enhanced Catalytic Reduction of p-Nitrophenol on Ultrathin MoS2 Nanosheets Decorated with Noble Metal Nanoparticles
    Qiao, Xiu-Qing
    Zhang, Zhen-Wei
    Tian, Feng-Yu
    Hou, Dong-Fang
    Tian, Zheng-Fang
    Li, Dong-Sheng
    Zhang, Qichun
    CRYSTAL GROWTH & DESIGN, 2017, 17 (06) : 3538 - 3547
  • [4] Effects of morphology and crystallinity of MoS2 nanocrystals on the catalytic reduction of p-nitrophenol
    Yang Li
    Qiushuang Chen
    Zhenwei Zhang
    Qiuhao Li
    Xiuqing Qiao
    Journal of Nanoparticle Research, 2018, 20
  • [5] Effects of morphology and crystallinity of MoS2 nanocrystals on the catalytic reduction of p-nitrophenol
    Li, Yang
    Chen, Qiushuang
    Zhang, Zhenwei
    Li, Qiuhao
    Qiao, Xiuqing
    JOURNAL OF NANOPARTICLE RESEARCH, 2018, 20 (12)
  • [6] Carbon-protected Au nanoparticles supported on mesoporous TiO2 for catalytic reduction of p-nitrophenol
    Ji, Tuo
    Li, Licheng
    Wang, Meng
    Yang, Zhuhong
    Lu, Xiaohua
    RSC ADVANCES, 2014, 4 (56): : 29591 - 29594
  • [7] Enhanced Reduction of p-Nitrophenol by a Methanogenic Consortium Promoted by Metallic Nanoparticles
    Cervantes, Francisco J.
    Luis Rodriguez-Lopez, Jose
    Pena-Martinez, Mariana
    Ascacio-Valdes, Juan A.
    Aguilar, Cristobal N.
    Bahena, Daniel
    WATER AIR AND SOIL POLLUTION, 2016, 227 (10):
  • [8] Enhanced Reduction of p-Nitrophenol by a Methanogenic Consortium Promoted by Metallic Nanoparticles
    Francisco J. Cervantes
    José Luis Rodríguez-López
    Mariana Peña-Martínez
    Juan A. Ascacio-Valdes
    Cristobal N. Aguilar
    Daniel Bahena
    Water, Air, & Soil Pollution, 2016, 227
  • [9] p-nitrophenol hydrogenation with Ir, Ni and Ir-Ni catalysts supported on TiO2
    Rojas Sarmiento, Hugo Alfonso
    Cubillos Lobo, Jairo Antonio
    Guerrero Araque, Diana Clemencia
    REVISTA FACULTAD DE INGENIERIA, UNIVERSIDAD PEDAGOGICA Y TECNOLOGICA DE COLOMBIA, 2012, 21 (32): : 63 - 72
  • [10] Hierarchical Pd@ZIFs as Efficient Catalysts for p-Nitrophenol Reduction
    Jiang, Hong
    Liu, Manman
    Zhou, Minghui
    Du, Yan
    Chen, Rizhi
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2021, 60 (42) : 15045 - 15055