Adsorption of carbon dioxide by coconut activated carbon modified with Cu/Ce

被引:28
|
作者
Li Fenrong [1 ]
Yi Honghong [1 ]
Tang Xiaolong [1 ]
Ning Ping [1 ]
Yu Qiongfen [1 ]
Kang Dongjuan [1 ]
机构
[1] Kunming Univ Sci & Technol, Coll Environm Sci & Engn, Kunming 650093, Peoples R China
关键词
adsorption; CO2; capture; Cu; Ce; rare earths; SEQUESTRATION; CAPTURE; CO2;
D O I
10.1016/S1002-0721(10)60375-4
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
A series of the coconut activated carbons (CAC) based absorbents modified with Cu and Ce (Cu/CAC, Cu/Ce/CAC) were prepared by impregnation technology for carbon dioxide capture. The adsocrption equilibriums of CO2 on Cu/CAC and Cu/Ce/CAC were measured. The results showed that the adsorption capacity of CO2 onto the activated carbon modified with Cu/Ce increased with the decreasing temperature in the same pressure. The adsorption capacity of CO2 on Cu/CAC was higher than that of the blank CAC, and compared with the Cu/CAC, the adsorption capacity of CO2 of Cu/Ce/CAC with the mass ratio of Cu/Ce=30 was improved at 298 and 303 K. In addition, the adsorption equilibrium data for CO2 at various temperatures was fitted to Langmuir, Freundlich and D-R isotherm models. It was found that the D-R equation was the best model for fitting the adsorption data on Cu/Ce/CAC at different temperatures.
引用
收藏
页码:334 / 337
页数:4
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