Sustainable Suzuki-Miyaura reaction catalyzed by Pd(OAc)2 immobilized on reversed-phase alumina

被引：7
|
作者：
Hagiwara, Hisahiro [1 ]
Ko, Keon Hyeok [1 ]
Hoshi, Takashi [2 ]
Suzuki, Toshio [2 ]
机构：
[1] Niigata Univ, Grad Sch Sci & Technol, Nishi Ku, Niigata 9502181, Japan
[2] Niigata Univ, Fac Engn, Nishi Ku, Niigata 9502181, Japan
来源：
SYNLETT | 2008年 / 04期
关键词：
arylations; boron; cross-coupling; heterogeneous catalysis; palladium; supported catalysis;
D O I：
10.1055/s-2008-1032081
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Employing Pd(OAC)(2) immobilized on amorphous N,N-diethylaminopropyl alumina, Suzuki-Miyaura coupling of aryl halide with arylboronic acid was realized in 50% aqueous ethanol at room temperature, which enabled repeated use up to four times in 96% average yield and achieved a turnover number of 15 000.
引用
收藏
页码：611 / 613
页数：3
相关论文
共 50 条
  • [1] Pd(OAc)2/DABCO-catalyzed Suzuki-Miyaura cross-coupling reaction in DMF
    Li, Jin-Heng
    Zhu, Qi-Ming
    Xie, Ye-Xiang
    [J]. TETRAHEDRON, 2006, 62 (47) : 10888 - 10895
  • [2] Speciation of Pd(OAc)2 in ligandless Suzuki-Miyaura reactions
    Adrio, Luis A.
    Nguyen, Bao N.
    Guilera, Gemma
    Livingston, Andrew G.
    Hii, King Kuok
    [J]. CATALYSIS SCIENCE & TECHNOLOGY, 2012, 2 (02) : 316 - 323
  • [3] Preparation and Application of WELAN to Pd(OAc)2-Catalyzed Suzuki-Miyaura Cross-Coupling Reaction
    Saikia, Bishwajit
    [J]. CATALYSIS LETTERS, 2024, : 6562 - 6567
  • [4] Immobilized, modular, and sterically demanding carbene ligands applied to the Pd catalyzed Suzuki-Miyaura reaction
    Claver, Carmen
    Castillon, Sergio
    Godard, Cyril
    Krinsky, Jamin L.
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2012, 244
  • [5] Speciation of Pd(OAc)2 in ligandless Suzuki-Miyaura reaction (vol 2, pg 316, 2012)
    Adrio, Luis A.
    Nguyen, Bao N.
    Guilera, Gemma
    Livingston, Andrew G.
    Hii, King Kuok
    [J]. CATALYSIS SCIENCE & TECHNOLOGY, 2012, 2 (12) : 2578 - 2578
  • [6] Efficient Pd(OAc)2/pyrimidine catalytic system for Suzuki-Miyaura cross-coupling reaction
    Li, JH
    Zhang, XD
    Xie, YX
    [J]. SYNLETT, 2005, (12) : 1897 - 1900
  • [7] Efficient Sonogashira and Suzuki-Miyaura coupling reaction catalyzed by Pd-Nanoparticles
    Balsane, Kishor E.
    Shendage, Suresh S.
    Nagarkar, Jayashree M.
    [J]. JOURNAL OF CHEMICAL SCIENCES, 2015, 127 (03) : 425 - 431
  • [8] Enhanced heterogeneously catalyzed Suzuki-Miyaura reaction over SiliaCat Pd(0)
    Pandarus, Valerica
    Desplantier-Giscard, Delphine
    Gingras, Genevieve
    Ciriminna, Rosaria
    Cara, Piera Demma
    Beland, Francois
    Pagliaro, Mario
    [J]. TETRAHEDRON LETTERS, 2013, 54 (35) : 4712 - 4716
  • [9] Efficient Sonogashira and Suzuki-Miyaura coupling reaction catalyzed by Pd-Nanoparticles
    KISHOR E BALSANE
    SURESH S SHENDAGE
    JAYASHREE M NAGARKAR
    [J]. Journal of Chemical Sciences, 2015, 127 : 425 - 431
  • [10] Very Fast Suzuki-Miyaura Reaction Catalyzed by Pd(OAc)2 under Aerobic Conditions at Room Temperature in EGME/H2O
    Del Zotto, Alessandro
    Amoroso, Francesco
    Baratta, Walter
    Rigo, Pierluigi
    [J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2009, 2009 (01) : 110 - 116
12345