Synthesis of Poly(propylene)/Graphite Nanocomposites by in Situ Polymerization

被引：25

作者：

Montagna, Larissa Stieven ^{[1
]}

Fim, Fabiana de Carvalho ^{[2
]}

Galland, Griselda Barrera ^{[2
]}

de Souza Basso, Nara Regina ^{[1
]}

机构：

[1] Pontificia Univ Catolica Rio Grande do Sul, Posgrad Program Mat Engn & Technol, Av Ipiranga 6681, BR-90619900 Porto Alegre, RS, Brazil

[2] Univ Fed Rio Grande Do Sul, Chem Inst, BR-91570970 Rio Grande Do Sul, RS, Brazil

来源：

BRAZILIAN POLYMER CONGRESS | 2011年 / 299-300卷

关键词：

graphite nanosheets; in situ polymerization; nanocomposites; poly(propylene); MECHANICAL-PROPERTIES; GRAPHITE; COMPOSITE;

D O I：

10.1002/masy.200900133

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

This work presents the synthesis of polypropylene/graphite nanocomposites by in situ polymerization using the catalytic system C20H16Cl2Zr (rac-ethylenebis (indenyl) zirconium(IV)) dichloride/Methyoluminoxane (MAO). 60 nm graphite nanosheets (GNS) were obtained by means of the chemical exfoliation, thermal and ultrasound treatment. GNS previously treated with MAO were added into the reactor at percentages of 0.3, 1.0 and 2.2% (w/w) in relation to nanocomposite yields. The morphology of graphite nanosheets and nanocomposites was studied by Scanning Electron Microscopy (SEM). Moreover, the structural properties of natural graphite flake (NGF), graphite nanosheets (GNS) and nanocomposites were observed through the X-Ray diffraction (XRD) analysis and by Transmission Electron Microscopy (TEM).

引用

页码：48 / 56

页数：9

共 50 条

[1] Synthesis, characterization and properties of poly(propylene-1-octene)/graphite nanosheet nanocomposites obtained by in situ polymerization
Milani, Marceo A.
Gonzalez, Dario
Quijada, Raul
Benavente, Rosario
Arranz-Andres, Javier
Galland, Griselda B.
[J]. POLYMER, 2015, 65 : 134 - 142
[2] Polyethylene/Graphite Nanocomposites Obtained by In Situ Polymerization
Fim, Fabiana de C.
Guterres, Jonathan M.
Basso, Nara R. S.
Galland, Griselda B.
[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2010, 48 (03) : 692 - 698
[3] Electrical conductivity of poly(ethylene terephthalate)/expanded graphite nanocomposites prepared by in situ polymerization
Paszkiewicz, S.
Szymczyk, A.
Spitalsky, Z.
Soccio, M.
Mosnacek, J.
Ezquerra, T. A.
Roslaniec, Z.
[J]. JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2012, 50 (23) : 1645 - 1652
[4] Synthesis and properties of poly(ethylene terephthalate)/clay nanocomposites by in situ polymerization
Kim, Se Hoon
Kim, Sung Chul
[J]. JOURNAL OF APPLIED POLYMER SCIENCE, 2007, 103 (02) : 1262 - 1271
[5] SYNTHESIS OF POLY(VINYL ACETATE)-INTERCALATED GRAPHITE OXIDE BY AN IN SITU INTERCALATIVE POLYMERIZATION
Ping-gui Liu
Peng Xiao
Min Xiao
Ke-cheng Gong Beijing Institute of Aeronautical Materials
[J]. Chinese Journal of Polymer Science, 2000, (05) : 413 - 418
[6] Synthesis of poly(vinyl acetate)-intercalated graphite oxide by an in situ intercalative polymerization
Liu, PG
Xiao, P
Xiao, M
Gong, KC
[J]. CHINESE JOURNAL OF POLYMER SCIENCE, 2000, 18 (05) : 413 - 418
[7] Synthesis and characterization of poly(methyl methacrylate)/montmorillonite nanocomposites by in situ bulk polymerization
Xie, TX
Yang, GS
Fang, XP
Ou, YC
[J]. JOURNAL OF APPLIED POLYMER SCIENCE, 2003, 89 (08) : 2256 - 2260
[8] Synthesis of poly(furfuryl alcohol)/montmorillonite nanocomposites by direct in-situ polymerization
Kherroub, Djamal Eddine
Belbachir, Mohammed
Lamouri, Saad
[J]. BULLETIN OF MATERIALS SCIENCE, 2015, 38 (01) : 57 - 63
[9] Synthesis of poly(furfuryl alcohol)/montmorillonite nanocomposites by direct in-situ polymerization
DJAMAL EDDINE KHERROUB
MOHAMMED BELBACHIR
SAAD LAMOURI
[J]. Bulletin of Materials Science, 2015, 38 : 57 - 63
[10] Kinetics of the in situ polymerization and in situ compatibilization of poly(propylene) and polyamide 6 blends
[J]. Hu, G.-H. (hu@ensic.inpl-nancy.fr), 1600, John Wiley and Sons Inc. (91):

← 1 2 3 4 5 →