The exotic potential curve of the 3(1)Pi(g) state of K-2 by optical-optical double-resonance spectroscopy

被引：5
|
作者：
Kim, JT
Wang, H
Bahns, JT
Stwalley, WC
机构：
[1] UNIV CONNECTICUT,INST MAT SCI,STORRS,CT 06269
[2] UNIV IOWA,DEPT PHYS & ASTRON,IOWA CITY,IA 52242
[3] UNIV IOWA,DEPT CHEM,IOWA CITY,IA 52242
来源：
JOURNAL OF MOLECULAR SPECTROSCOPY | 1997年 / 181卷 / 02期
关键词：
D O I：
10.1006/jmsp.1996.7195
中图分类号：
O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号：
070203 ; 070304 ; 081704 ; 1406 ;
摘要：
The Rydberg-Klein-Rees potential curve of the 3(1) Pi(g), state which covers the internuclear distance from 3.59926 to 6.76571 Angstrom is constructed from the experimentally determined B-nu and G(nu) values. The predicted exotic shape (change in slope outside similar to 5.7 Angstrom) agrees with the experimental results. The dissociation energy of this state which dissociates to the K(4s) + K(5p) atomic asymptotic limit is determined to be 2731.292 +/- 0.085 cm(-1). (C) 1997 Academic Press.
引用
收藏
页码：389 / 393
页数：5
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