Superamphiphilic Chitosan Cryogels for Continuous Flow Separation of Oil-In-Water Emulsions

Chitosan is a typical hydrophilic biomass building block widely used in material science and engineering. However, its intrinsic amphiphilicity has been seldom noted so far. Herein, a series of glutaraldehyde-crosslinked chitosan cryogels with superamphiphilicity are fabricated at moderately frozen conditions through a freezing-thawing process. The micron-sized porous cryogel samples display a 0 degrees contact angle toward both water and oil, 0 degrees water contact angle under oil, and over 120 degrees oil contact angle underwater. By comparing the wetting behavior of the tablet compressed by pure chitosan powders, the superamphiphilicity of the chitosan sample is proven to be independent on crosslinkers. This special wettability endows the chitosan cryogels with high separation efficiency for various surfactant-stabilized oil-in-water emulsions under continuous flow mode driven by gravity as well as a peristaltic pump.