In-Line Monitoring of SBR Emulsion Polymerization Using ATR-FTIR Spectroscopy

被引：16
|
作者：
Dube, Marc A. [1 ]
Li, Liang [1 ]
机构：
[1] Univ Ottawa, Dept Chem & Biol Engn, Ottawa, ON K1N 6N5, Canada
来源：
POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING | 2010年 / 49卷 / 07期
基金：
加拿大自然科学与工程研究理事会;
关键词：
1,3-butadiene; H-1-NMR spectroscopy; ATR-FTIR spectroscopy; Emulsion polymerization; In-line monitoring; Styrene; COPOLYMERIZATIONS; MINIEMULSION; ACRYLATE; STYRENE;
D O I：
10.1080/03602551003664909
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The copolymerization of styrene/1,3-butadiene in emulsion was monitored in-line using an ATR-FTIR spectroscopic probe. The concentration of monomers was monitored to provide real-time conversion and copolymer composition data. Traditional off-line techniques, gravimetry and H-1-NMR spectroscopy, were compared to the in-line ATR-FTIR data. A multivariate calibration method using the full reaction spectra displayed no significant differences between the off-line and in-line data sets at a 95% confidence level. It was demonstrated that ATR-FTIR spectroscopy is a reliable tool for monitoring conversion and polymer composition in multi-phase emulsion polymerizations.
引用
下载
收藏
页码：648 / 656
页数：9
相关论文
共 50 条
  • [1] In-line monitoring of butyl acrylate/vinyl acetate emulsion copolymerizations using ATR-FTIR spectroscopy
    Jovanovic, R
    Dubé, MA
    POLYMER REACTION ENGINEERING, 2003, 11 (03): : 233 - 257
  • [2] In-line monitoring of emulsion homo- and copolymerizations using ATR-FTIR spectrometry
    Hua, H
    Dubé, MA
    POLYMER REACTION ENGINEERING, 2002, 10 (1-2): : 21 - 40
  • [3] In-line monitoring of reactive crystallization process based on ATR-FTIR and Raman spectroscopy
    Alatalo, Hannu
    Kohonen, Jarno
    Qu, Haiyan
    Hatakka, Henry
    Reinikainen, Satu-Pia
    Louhi-Kultanen, Marjatta
    Kallas, Juha
    JOURNAL OF CHEMOMETRICS, 2008, 22 (11-12) : 644 - 652
  • [4] Terpolymerization monitoring with ATR-FTIR spectroscopy
    Hua, H
    Dubé, MA
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2001, 39 (11) : 1860 - 1876
  • [5] Reaction Monitoring of Glycerol Step-Growth Polymerization Using ATR-FTIR Spectroscopy
    Salehpour, Somaieh
    Dube, Marc A.
    MACROMOLECULAR REACTION ENGINEERING, 2012, 6 (2-3) : 85 - 92
  • [6] ATR-FTIR spectroscopy for in-line anomer concentration measurements in solution: A case study of lactose
    Schiele, Simon A.
    Meinhardt, Rolf
    Eder, Cornelia
    Briesen, Heiko
    FOOD CONTROL, 2020, 110
  • [7] Off-line monitoring of styrene/butyl acrylate copolymerizations in toluene using ATR-FTIR spectroscopy
    Hua, H
    Rivard, T
    Dubé, MA
    POLYMER, 2004, 45 (02) : 345 - 354
  • [8] Recent advances and applications to cultural heritage using ATR-FTIR spectroscopy and ATR-FTIR spectroscopic imaging
    Liu, Guan-Lin
    Kazarian, Sergei G.
    ANALYST, 2022, 147 (09) : 1777 - 1797
  • [9] Bioprocess monitoring applications of an innovative ATR-FTIR spectroscopy platform
    Christie, Loren
    Rutherford, Samantha
    Palmer, David S.
    Baker, Matthew J.
    Butler, Holly J.
    FRONTIERS IN BIOENGINEERING AND BIOTECHNOLOGY, 2024, 12
  • [10] ATR-FTIR Spectroscopy of immobilized proteins
    Koetting, Carsten
    Gueldenhaupt, Joern
    Pinkerneil, Philipp
    Gerwert, Klaus
    EUROPEAN BIOPHYSICS JOURNAL WITH BIOPHYSICS LETTERS, 2011, 40 : 52 - 52
12345