BIS(N,N′-BIS(2-HYDROXYETHYL)ETHYLENEDIAMINE)NICKEL(II) SACCHARINATE: SYNTHESIS, CHARACTERIZATION AND CRYSTAL STRUCTURE

被引：1
|
作者：
Karadogan, Alparslan [1 ]
Karadag, Ahmet [1 ]
Yilmaz, Veysel T. [2 ]
机构：
[1] Gaziosmanpasa Univ, Fac Arts & Sci, Dept Chem, Tokat, Turkey
[2] Uludag Univ, Fac Arts & Sci, Dept Chem, TR-16059 Bursa, Turkey
来源：
MACEDONIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING | 2015年 / 34卷 / 01期
关键词：
saccharinate; N; '-bis(2-hydroxyethyl)ethylenediamine; nickel(II); crystal structure; COMPLEXES;
D O I：
10.20450/mjcce.2015.651
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new nickel(II) saccharinate (sac) complex containing N,N'-bis(2-hydroxyethyl)ethylenediamine (bishydeten), [Ni(bishydeten)(2)](sac)(2), has been synthesized and characterized by elemental analysis, FTIR. and single crystal X-ray diffraction. The title complex consists of a [Ni(bishydeten)(2)](2+) cation and two sac anions. In the complex cation, the nickel(II) ion is coordinated by two neutral bishydeten ligands, leading to a distorted octahedral NiN4O2 coordination, while both sac anions remain outside the coordination sphere. In the crystal, the complex cations and sac anions are connected by an extensive network of N-H center dot center dot center dot N, N-H center dot center dot center dot O, O-H center dot center dot center dot O and C-H center dot center dot center dot O hydrogen bonds into a three-dimensional supramolecular lattice.
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收藏
页码：101 / 104
页数：4
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