Synthesis, structures and optical properties of trisilasumanene and its related compounds

被引:54
|
作者
Tanikawa, Tomoharu [1 ]
Saito, Masaichi [1 ]
Guo, Jing Dong [2 ]
Nagase, Shigeru [2 ]
机构
[1] Saitama Univ, Grad Sch Sci & Engn, Dept Chem, Sakura Ku, Saitama 3388570, Japan
[2] Natl Inst Nat Sci, Inst Mol Sci, Dept Theoret & Computat Mol Sci, Okazaki, Aichi 4448585, Japan
关键词
SUMANENE; PI; POLYMERS;
D O I
10.1039/c0ob00987c
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Novel trisilasumanenes that have no substituents on the exo carbon atoms, silicon analogues of sumanene, were prepared via repetitive lithiations of triphenylene followed by introduction of silicon functionalities. The optical properties of these trisilasumanenes and their related compounds were investigated by UV-vis and fluorescence spectroscopy.
引用
收藏
页码:1731 / 1735
页数:5
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