Synthesis of high-performance green nanocomposites from renewable natural oils

被引：42
|
作者：
Tsujimoto, Takashi [1 ]
Uyama, Hiroshi [1 ]
Kobayashi, Shiro [2 ]
机构：
[1] Osaka Univ, Grad Sch Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan
[2] Kyoto Univ, Grad Sch Engn, Dept Chem Mat, Kyoto 6158510, Japan
来源：
POLYMER DEGRADATION AND STABILITY | 2010年 / 95卷 / 08期
关键词：
Bio-based polymers; Epoxidized natural oil; Nanocomposite; Silane coupling agent; NETWORK STRUCTURE; SOYBEAN OIL; RESOURCES; POLYMERIZATION; COMPOSITES; COATINGS; HYBRIDS; ACIDS;
D O I：
10.1016/j.polymdegradstab.2010.01.016
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
This paper describes preparation and properties of green nanocomposites from renewable resources. The nanocomposites were synthesized by an acid-catalyzed curing of epoxidized natural oils in the presence of silane coupling agents. The resulting nanocomposites were transparent and highly glossy. Their hardness and Young's modulus of the nanocomposite coatings improved, as compared with those only from the epoxidized natural oils. Dynamic viscoelasticity analysis and TEM observation showed the homogeneous structure of the nanocomposites. The properties of the nanocomposites were strongly affected by the structure and feed ratio of the monomers. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码：1399 / 1405
页数：7
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