The germanium(II) ate complex [Ph3PiPr][Ge(OCOMe)3]:: the first structurally characterized compound containing a discrete [E14(II)O3](-) (E14(II) = Si, Ge, Sn or Pb) anion

被引：2

作者：

Khrustalev, VN

Antipin, MY

Zemlyansky, NN

Borisova, IV

Ustynyuk, YA

Lunin, VV

Izod, K

机构：

[1] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia

[2] Russian Acad Sci, AV Topchiev Petrochem Synth Inst, Moscow 119991, Russia

[3] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119899, Russia

[4] Univ Newcastle, Sch Nat Sci, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England

来源：

APPLIED ORGANOMETALLIC CHEMISTRY | 2005年 / 19卷 / 03期

关键词：

germanium(II); acetate; ate complex; crystal structure;

D O I：

10.1002/aoc.825

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

An X-ray diffraction study reveals an unusual structure of the new thermally stable germanium(II) ate complex [(Ph3PPr)-Pr-i][Ge(OAc)(3)] (4) containing a discrete [Ge(OAc)(3)]((-)) anion containing monodentate acetate ligands with a trigonal pyramidal germanium centre. Copyright (c) 2005 John Wiley & Sons, Ltd.

引用

页码：360 / 362

页数：3

共 8 条

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Khrustalev, VN
Antipin, MY
Zemlyansky, NN
Borisova, IV
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Lunin, VV
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[2] New stable germylenes, stannylenes, and related compounds.: 5.: Germanium(II) and tin(II) azides [N3-E14-OCH2CH2NMe2]2 (E14 = Ge, Sn):: synthesis and structure
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[3] New stable germylenes, stannylenes, and related compounds 6.: Heteroleptic germanium(II) and tin(II) compounds [(SiMe3)2N-E14-OCH2CH2NMe2]n (E14 = Ge, n = 1; Sn, n = 2):: synthesis and structure
Khrustalev, VN
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[4] The ate complexes [M{C(SiMe3)3}(μ-SBu)2Li(THF)2] (M = Ge or Sn).: The first structural characterization of organometallic ate complexes of group 14 metals in oxidation state II
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[5] The structure and chemical transformations of betaines Me2E14(-)-CH2-(+)E15Me3 (E14 = Si, Ge, and Sn and E15 = P and As) and the reaction between 1,3-Di(ter-butyl)-2,3-dihydro-1H-1,3,2-diazasilol-2-ilidene and trimethylmethylenephosphorane
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[6] New Stable Germylenes, Stannylenes, and Related Compounds II. Bis(butylthio)tin(II) and ate-Complexes [(Me3Si)3CE(μ-SBu)2Li(THF)2] (E = Ge,Sn). Synthesis and Structure
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[7] New stable germylenes, stannylenes, and related compounds II.: Bis(butylthio)tin(II) and ate-complexes [(Me3Si)3CE(μ-SBu)2Li(THF)2] (E = Ge,Sn).: Synthesis and structure
Zemlyanskii, NN
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[J]. RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2003, 39 (04) : 491 - 500
[8] Synthesis of iridium complexes bearing {o-(Ph2P)C6H4}3E type (E = Si, Ge, and Sn) ligand and evaluation of electron donating ability of group 14 elements E
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[J]. DALTON TRANSACTIONS, 2012, 41 (27) : 8290 - 8296

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