Recent advances in the functionalization of allenes via radical process

被引：43
|
作者：
Qiu, Guanyinsheng [1 ,2 ]
Zhang, Jun [2 ]
Zhou, Kaida [2 ]
Wu, Jie [2 ,3 ]
机构：
[1] Jiaxing Univ, Coll Biol Chem Sci & Engn, 118 Jiahang Rd, Jiaxing 314001, Peoples R China
[2] Fudan Univ, Dept Chem, 2005 Songhu Rd, Shanghai 200438, Peoples R China
[3] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, 345 Lingling Rd, Shanghai 200032, Peoples R China
来源：
TETRAHEDRON | 2018年 / 74卷 / 51期
基金：
中国博士后科学基金; 中国国家自然科学基金;
关键词：
Allene; Heteroatom radical; Carbon radical; Regioselectivity; Stereoselectivity; VISIBLE-LIGHT PHOTOREDOX; COPPER-CATALYZED TRIFLUOROMETHYLATION; PERFLUOROALKYL IODIDES; ADDITION REACTION; EFFICIENT SYNTHESIS; KINETIC RESOLUTION; DIAZONIUM SALTS; HECK REACTION; CYCLIZATIONS; IRRADIATION;
D O I：
10.1016/j.tet.2018.10.061
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
This review is focused on the recent advances in the functionalization of allenes via radical process. Different radical partners including carbon radicals and heteroatom radicals are discussed in the reactions of allenes. Generally, the radical formed in situ would attack the allene at the central carbon leading to allyl radical intermediate. However, the formation of alkenyl radical intermediate from allene could be observed as well in some cases with high regioselectivity and stereoselectivity. (C) 2018 Elsevier Ltd. All rights reserved.
引用
收藏
页码：7290 / 7301
页数：12
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