Syntheses and crystal structures of Sr7H12X2 (X = Cl, Br)

被引：14

作者：

Reckeweg, Olaf ^{[1
]}

Molstad, Jay C. ^{[1
]}

Levy, Scott ^{[1
]}

Hoch, Constantin ^{[2
]}

Disalvo, Francis J. ^{[1
]}

机构：

[1] Cornell Univ, Baker Lab, Dept Chem & Chem Biol, Ithaca, NY 14853 USA

[2] Max Planck Inst Festkorperforsch, D-70569 Stuttgart, Germany

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2008年 / 63卷 / 05期

关键词：

strontium; bromide; chloride; hydride; synthesis; structure elucidation; EUTAX calculations;

D O I：

10.1515/znb-2008-0506

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Dichroic, pink to blue single crystals of Sr7H12Cl2 and Sr7H12Br2 were obtained by reacting Sr with SrX2 or NaX and NaNH2 or NH4X (X = Cl, Br) as hydrogen sources in a Na melt at 900 degrees C for 12 h in silica-jacketed stainless-steel or Ta ampoules. The crystal structures of the new compounds were determined by means of single crystal X-ray diffraction. Both title compounds crystallize isotypically to Ba7Cl2F12 in the hexagonal space group P (6) over bar (no. 174) with the lattice parameters a = 998.06(3), c = 392.84(3) pm for Sr7H12Cl2 and a = 1004.62(3), c = 399.68(3) pm for Sr7H12Br2. The hydride positions taken from the difference Fourier map agree with those of the fluorides of the isotypic compound Ba7F12Cl12. The validity of our structural results is corroborated by EUTAX calculations and the comparison to SrH2, SrX2 and SrHX.

引用

页码：513 / 518

页数：6

共 50 条

[1] Syntheses and crystal structures of the new ternary barium halide hydrides Ba2H3X (X = Cl or Br)
Reckeweg, Olaf
Molstad, Jay C.
Levy, Scott
DiSalvo, Francis J.
[J]. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2007, 62 (01): : 23 - 27
[2] CRYSTAL-STRUCTURES OF COMPOUNDS A2X2(A=S,SE - X=CL,BR)
KNIEP, R
KORTE, L
MOOTZ, D
[J]. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1983, 38 (01): : 1 - 6
[3] Zintl Salts Ba2P7X ( X = Cl, Br, and I): Synthesis, Crystal, and Electronic Structures
Dolyniuk, Juli-Anna
Kovnir, Kirill
[J]. CRYSTALS, 2013, 3 (03): : 431 - 442
[4] New Calcium Hydride Halides with Familiar Structures. Syntheses and Crystal Structures of Ca7H12Cl2 and Ca2H3Br
Reckeweg, Olaf
DiSalvo, Francis J.
[J]. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2010, 65 (04): : 493 - 498
[5] Syntheses, crystal structures, and electronic structure of the boron halides B9X9 (X = Cl, Br, I)
Honle, W
Grin, Y
Burkhardt, A
Wedig, U
Schultheiss, M
vonSchnering, HG
Kellner, R
Binder, H
[J]. JOURNAL OF SOLID STATE CHEMISTRY, 1997, 133 (01) : 59 - 67
[6] Syntheses, Crystal Structures, and Vibrational Properties of Two Lead Azide Halides PbN3X (X = Cl, Br)
Liu, Xiaohui
Stoffel, Ralf
Dronskowski, Richard
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2020, 646 (18): : 1525 - 1530
[7] Superacidity of Boron Acids H2(B12X12) (X = Cl, Br)
Avelar, Amy
Tham, Fook S.
Reed, Christopher A.
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (19) : 3491 - 3493
[8] Sr2P7X (X = Cl, Br, and I): Synthesis, Crystal and Electronic Structures of Double Zintl Salts Containing Heptaphosphanortricyclane, P73-
Dolyniuk, Juli-Anna
Tran, Nhon
Lee, Kathleen
Kovnir, Kirill
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2015, 641 (8-9): : 1422 - 1427
[9] Structures and bonding situation of Pb2X2 (X = H, F, Cl, Br and I)
Taka Shimizu
Gernot Frenking
[J]. Theoretical Chemistry Accounts, 2011, 130 : 269 - 277
[10] Structures and bonding situation of Pb2X2 (X = H, F, Cl, Br and I)
Shimizu, Taka
Frenking, Gernot
[J]. THEORETICAL CHEMISTRY ACCOUNTS, 2011, 130 (2-3) : 269 - 277

← 1 2 3 4 5 →