Physical and structural properties of the Ni(DMIT)2 ladder chain

被引:2
|
作者
Imai, H [1 ]
Naito, T
Awaga, K
Inabe, T
机构
[1] Inst Mol Sci, Dept Appl Mol Sci, Okazaki, Aichi 4448585, Japan
[2] Hokkaido Univ, Grad Sch Sci, Div Chem, Sapporo, Hokkaido 0600810, Japan
[3] Univ Tokyo, Grad Sch Arts & Sci, Dept Basic Sci, Tokyo 1530041, Japan
关键词
magnetic measurements; X-ray diffraction;
D O I
10.1016/S0379-6779(00)00615-9
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The magnetic and crystal structures of the [Ni(dmit)(2)](-) (dmit = 1,3-dithiol-1,2-thione-4,5-dithiolate) simple salts with N-alkylated cationic derivatives of pyridyl nitronyl nitroxide radical (N-R-PYNN) have been studied. In the system with p-nBuPYNN (p-N-nbutyl-), [Ni(dmit)(2)](-) is found to form ladder chains similar with those found in p-EPYNN[Ni(dmit)(2)]. The magnetic susceptibility in this salt shows spin-ladder behavior.
引用
收藏
页码:951 / 952
页数:2
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