Model studies toward the synthesis of natural indans utilizing a thallium(III)-mediated ring-contraction reaction

被引：0

作者：

Ferraz, HMC ^{[1
]}

Aguilar, AM ^{[1
]}

Silva, LF ^{[1
]}

机构：

[1] Univ Sao Paulo, Inst Quim, BR-05513970 Sao Paulo, Brazil

来源：

SYNTHESIS-STUTTGART | 2003年 / 07期

关键词：

indan; jungianol; mutisianthol; ring contraction; thallium trinitrate;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

6-Methoxy-1-tetralone was transformed in six steps into an indan derivative related to the sesquiterpenes mutisianthol and jungianol. Key steps involve a thallium(III)-promoted ring-contraction (to assemble the indan unit) and a Wittig olefination (to attach the side chain).

引用

页码：1031 / 1034

页数：4

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