Vibrational spectra of dimethyldithiophosphinate anion:: (CH3)2PS2-

被引：1
|
作者：
Tellez, CA
de la Riva, S
Hollauer, E
Haiduc, I
Silvestru, CS
机构：
[1] Pontificia Univ Catolica Rio de Janeiro, Dept Quim, BR-22453900 Rio De Janeiro, RJ, Brazil
[2] Univ Fed Fluminense, Dept Quim Fis, BR-24210150 Rio De Janeiro, Brazil
[3] Univ Babes Bolyai, Dept Chem, R-3400 Cluj Napoca, Romania
来源：
SPECTROSCOPY LETTERS | 1998年 / 31卷 / 07期
关键词：
D O I：
10.1080/00387019808001653
中图分类号：
O433 [光谱学];
学科分类号：
0703 ; 070302 ;
摘要：
The infrared and Raman spectra of dimethyldithiophosphinate anion (CH3)(2)PS2- were measured and the vibrational modes for the anion complex were assigned. A Normal Coordinate Analysis in the Modified General Valence Force Field (MGVFF) approximation was carried out assuming C-2v symmetry. At, Initio Calculations at RHF and MP2 level were also carried out for the anion geometry as well as for its frequencies, intensities and force constants.
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收藏
页码：1469 / 1483
页数：15
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