Enhancement of a two-photon absorption cross section (TPACS) - design and synthesis of a novel class of photochromic molecules with large TPACS

被引:8
|
作者
Pan, GL
Fan, MG [1 ]
Fan, P
Wang, HZ
Wei, ZC
机构
[1] Chinese Acad Sci, Tech Inst Phys & Chem, Beijing 100101, Peoples R China
[2] Zhongshan Univ, State Key Lab Ultrafast Laser Spect, Guangzhou 510275, Peoples R China
关键词
D O I
10.1039/b102876f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Two novel photochromic compounds were designed and synthesized; the two-photon absorption (TPA) cross section of both were measured with a nanosecond laser pulse; their TPACS (delta) values are around 25 x 10(-46) cm(4) S photon(-1) molecule(-1) in acetonitrile; the molecular structure of the target compounds have a 3-methyl-1-benzothiophen-2-yl moiety, which can greatly enhance the two-photon absorption cross section.
引用
收藏
页码:1744 / 1745
页数:2
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