Synthesis, characterization and properties of polyesteramides based on ε-caprolactone and 6-aminocaproic acid

被引:7
|
作者
He, Yi [1 ]
Du, Youru [2 ]
Liu, Xiaobo [3 ]
机构
[1] SW Petr Univ, State Key Lab Oil & Gas Reservoir Geol & Exploita, Rd 8, Chengdu 610500, Sichuan Provinc, Peoples R China
[2] SW Petr Univ, Inst Chem & Chem Engn, Chengdu 610500, Peoples R China
[3] Univ Elect Sci & Technol China, Key Lab Elect Thin Films & Integrated Devices, Chengdu, Peoples R China
来源
关键词
Biodegradable polyesteramides; Thermal property; Mechanical properties; Thermal degradation; POLY(ESTER AMIDE)S; 11-AMINOUNDECANOIC ACID; HYDROLYTIC DEGRADATION; ANIONIC COPOLYMERS; AMINO-ACIDS; LACTIC-ACID; COPOLYESTERAMIDES; POLYMERS;
D O I
10.4028/www.scientific.net/AMR.287-290.1538
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Biodegradable aliphatic polyesteramides were synthesized from e-caprolactone and 6-aminocaproic acid by melt-polycondensation method. FTIR, 1H-NMR, DSC, WAXD, TG, and tensile testing were used to characterize the polyesteramides. With the increase in 6-aminocaproic acid content, the melting temperature, thermal degradation temperature and tensile strength at break increased accordingly. The ester bond decomposes at lower temperature, and then the amide bond decomposes at higher temperature.
引用
收藏
页码:1538 / +
页数:2
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