Cleavable double-chain surfactant Co(III) complexes

被引：13
|
作者：
Jaeger, DA [1 ]
Reddy, VB [1 ]
Bohle, DS [1 ]
机构：
[1] Univ Wyoming, Dept Chem, Laramie, WY 82071 USA
来源：
TETRAHEDRON LETTERS | 1999年 / 40卷 / 04期
基金：
美国国家科学基金会;
关键词：
cleavage reactions; cobalt and compounds; photochemistry; surfactants;
D O I：
10.1016/S0040-4039(98)02511-8
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Double-chain surfactant Co(III) complexes 1 and 2 have been cleaved in H2O by reduction with Na2S2O4 under mild conditions or by irradiation at 354 nm or with sunlight. In each case, cleavage derives from the reduction of substitutionally inert Co(III) to substitutionally labile Co(II). (C) 1999 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：649 / 652
页数：4
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