Bis(μ-3,5-dinitrobenzoato-κ2O1:O1′)bis(μ-3,5-dinitrobenzoato)-κ3O1,O1′:O1;κ3O1:O1,O1′-bis[(3,5-dinitrobenzoato-κ2O1,O1′)(1,10-phenanthroline-κ2N,N)dysprosium(III)]

被引:0
|
作者
Dong, Chun-Hua [1 ]
Zhang, Da-Hai [1 ]
Ren, Ning [1 ]
Xi, Gai-Qing [1 ]
Hao, Juan-Juan [1 ]
机构
[1] Handan Coll, Dept Chem, Handan 056005, Hebei, Peoples R China
基金
美国国家科学基金会;
关键词
D O I
10.1107/S1600536810052001
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the binuclear title complex, [Dy-2(C7H3N2O6)(6)(C12H8N2)(2)], the Dy-III ions exhibit a distorted monocapped square-antiprismatic geometry and are coordinated by seven O atoms of four 3,5-dinitrobenzoate (DNBA) anions and two N atoms of a phenanthroline ligand. The carboxylate groups of the DNBA anions exhibit three coordination modes: bidentate chelating, bidentate chelating-bridging and tridentate chelating-bridging. The center of the molecule is located on a crystallographic center of inversion.
引用
收藏
页码:M102 / U1070
页数:16
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