Zirconium and titanium complexes with side-chain functionalized cyclopentadienyl ligands

被引：9
|
作者：
Krut'ko, D. P. [1 ]
机构：
[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119992, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2009年 / 58卷 / 09期
关键词：
zirconium; titanium; side-chain functionalized cyclopentadienyl ligands; reduction reactions; activation of unreactive bonds; dynamic behavior in solution; NMR spectroscopy; SUBSTITUTED ZIRCONOCENE DICHLORIDES; REDUCTIVE ELIMINATION-REACTIONS; CRYSTAL-STRUCTURE; CATALYTIC HYDROAMINATION; DINITROGEN COMPLEXES; DYNAMIC-BEHAVIOR; BOND ACTIVATION; PENDANT ETHER; BEARING; HYDROGENATION;
D O I：
10.1007/s11172-009-0242-9
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The present review summarizes the results of studies of Zr and Ti complexes based on chelating side-chain functionalized cyclopentadienyl ligands, which were synthesized by the author of the present review and co-workers. The coordination ability of the functional groups is considered. Dynamic processes that occur in half-sandwich complexes in solutions were studied by NMR spectroscopy. Emphasis is given to the reduction reactions of side-chain functionalized zirconocene dichlorides, as well as to the structures and properties of the reaction products depending on the nature of the heteroatomic substituent.
引用
收藏
页码：1745 / 1771
页数：27
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