A NEW SYNTHETIC STRATEGY FOR 2-DEOXY-D-RIBOSE VIA PALLADIUM(II)-CATALYZED CYCLIZATION OF ALDEHYDE

被引：5

作者：

Miyazawa, Masahiro ^{[1
]}

Awasaguchi, Ken-ichiro ^{[1
]}

Uoya, Ikuyo ^{[1
]}

Yokoyama, Hajime ^{[1
]}

Hirai, Yoshiro ^{[1
]}

机构：

[1] Toyama Univ, Grad Sch Sci & Technol, Toyama 9308555, Japan

来源：

HETEROCYCLES | 2010年 / 81卷 / 08期

关键词：

Carbohydrate; Hemiacetal; Tetrahydropyran; Stereoselectivity; Anomeric Effect; STEREOCONTROLLED CYCLIZATION; N-ALKYLATION; CONSTRUCTION; URETHANES; EFFICIENT; AGENTS; ACID;

D O I：

10.3987/COM-10-11988

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We achieved a total synthesis of 2-deoxy-D-ribose through intramolecular Pd(II)-catalyzed cyclization of aldehyde via an unstable hemiacetal intermediate as a key step.

引用

页码：1891 / 1902

页数：12

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