Cobalt-rhodium heterobimetallic nanoparticle-catalyzed reactions

被引：32
|
作者：
Park, Ji Hoon
Chung, Young Keun [1 ]
机构：
[1] Seoul Natl Univ, Intelligent Textile Syst Res Ctr, Seoul 151747, South Korea
来源：
DALTON TRANSACTIONS | 2008年 / 18期
关键词：
D O I：
10.1039/b718609f
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Transition metal nanoparticles have attracted a great deal of attention. This review discusses the synthesis of heterobimetallic cobalt-rhodium nanoparticles and their use as catalysts in organic transformations. Co-Rh nanoparticles (Co2Rh2) with a fixed stoichiometry (2 : 2) were easily obtained from Co2Rh2(CO)(12). These nanoparticles were quite effective catalysts for carbonylation reactions. Particularly, special focus is paid to the Pauson-Khand-type reaction.
引用
收藏
页码：2369 / 2378
页数：10
相关论文
共 50 条
  • [1] Cobalt-Rhodium Heterobimetallic Nanoparticle-Catalyzed N-Alkylation of Amines with Alcohols to Secondary and Tertiary Amines
    Chung, Hyunho
    Chung, Young Keun
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2018, 83 (15): : 8533 - 8542
  • [2] Cobalt-rhodium heterobimetallic nanoparticle-catalyzed synthesis of α,β-unsaturated amides from internal alkynes, amines, and carbon monoxide
    Park, Ji Hoon
    Kim, Sun Young
    Kim, Soo Min
    Chung, Young Keun
    [J]. ORGANIC LETTERS, 2007, 9 (13) : 2465 - 2468
  • [3] Heterobimetallic Cobalt/Rhodium Nanoparticle-Catalyzed Carbonylative Cycloaddition of 2-Alkynylanilines to Oxindoles
    Park, Ji Hoon
    Kim, Eunha
    Chung, Young Keun
    [J]. ORGANIC LETTERS, 2008, 10 (21) : 4719 - 4721
  • [4] Bimetallic Cobalt-Rhodium Nanoparticle-Catalyzed Reductive Amination of Aldehydes with Nitroarenes Under Atmospheric Hydrogen
    Choi, Isaac
    Chun, Supill
    Chung, Young Keun
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2017, 82 (23): : 12771 - 12777
  • [5] Hydrogen-Free Cobalt-Rhodium Heterobimetallic Nanoparticle-Catalyzed Reductive Amination of Aldehydes and Ketones with Amines and Nitroarenes in the Presence of Carbon Monoxide and Water
    Park, Jang Won
    Chung, Young Keun
    [J]. ACS CATALYSIS, 2015, 5 (08): : 4846 - 4850
  • [6] Immobilized cobalt/rhodium heterobimetallic nanoparticle-catalyzed silylcarbocylization and carbonylative silylcarbocyclization of 1,6-enynes
    Park, KH
    Jung, IG
    Kim, SY
    Chung, YK
    [J]. ORGANIC LETTERS, 2003, 5 (26) : 4967 - 4970
  • [7] Allenic Pauson-Khand reaction catalyzed by cobalt-rhodium heterobimetallic nanoparticles
    Park, Ji Hoon
    Kim, Sun Young
    Kim, Soo Min
    Lee, Sang Ick
    Chung, Young Keun
    [J]. SYNLETT, 2007, (03) : 453 - 459
  • [8] Chiral Rhodium Nanoparticle-Catalyzed Asymmetric Arylation Reactions
    Yasukawa, Tomohiro
    Miyamura, Hiroyuki
    Kobayashi, Shu
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 2020, 53 (12) : 2950 - 2963
  • [9] Cobalt/Rhodium Heterobimetallic Nanoparticle-Catalyzed Oxidative Carbonylation of Amines in the Presence of Carbon Monoxide and Molecular Oxygen to Ureas
    Park, Ji Hoon
    Yoon, Jae Chun
    Chung, Young Keun
    [J]. ADVANCED SYNTHESIS & CATALYSIS, 2009, 351 (09) : 1233 - 1237
  • [10] Heterogenized Catalysts Containing Cobalt-Rhodium Heterobimetallic Nanoparticles for Olefin Hydroformylation
    Kim, Jee Young
    Park, Ji Hoon
    Jung, Ok-Sang
    Chung, Young Keun
    Park, Kang Hyun
    [J]. CATALYSIS LETTERS, 2009, 128 (3-4) : 483 - 486
12345