Thiocyanatochrome complexes in analytical chemistry. Determination of osmium(III)

被引：3

作者：

Bratulescu, G ^{[1
]}

Ganescu, I ^{[1
]}

Ganescu, A ^{[1
]}

机构：

[1] Univ Craiova, Fac Chem, Craiova 1100, Romania

来源：

JOURNAL OF THE SERBIAN CHEMICAL SOCIETY | 2005年 / 70卷 / 8-9期

关键词：

complexes of Os(III) and of Cr(III); amines; analytical dosing;

D O I：

10.2298/JSC0509113B

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

New complex combinations of Os(III) complexed with thiourea and ethyl thiourea, as well as of complex anions of Cr(III) analogues of Reineke's salt, [Cr(CNS)(4)(amine)(2)](-), where the amine is aniline, benzylamine, morpholine etc., were synthesized. New gravimetric, oxidimetric and spectrophotometric analytical methods are proposed for the determination of Os(III). The experimental data were statistically processed and are not affected by systematic errors.

引用

页码：1113 / 1119

页数：7

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