Di-μ-nitrato-κ3O,O′:O";κ3O:O′,O"-bis[bis(3-nitrobenzohydrazide-κ2N′,O)cadmium(II)] dinitrate

被引：0
|
作者：
Chundak, S. Yu.
Lukachinec, L. Yu.
Daszkiewicz, M. [1 ]
机构：
[1] Uzhgorod State Univ, Fac Chem, UA-294000 Uzhgorod, Ukraine
[2] Uzhgorod State Univ, Fac Chem, Uzhgorod, Ukraine
[3] Polish Acad Sci, W Trzebiatowski Inst Low Temp & Struct Res, PL-50950 Wroclaw, Poland
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2007年 / 63卷
关键词：
D O I：
10.1107/S1600536807053792
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, [Cd-2(NO3)(2)(C7H7N3O3)(2)](NO3)(2), contains centrosymmetric dimeric cations in which two nitrate anions each serve as a bidentate ligand to one Cd atom and a bridge to the other. The other anion in the asymmetric unit (half the formula unit) is uncoordinated. The ligands form an atypical seven- coordinated augmented trigonal prism around the Cd-II atom, with a displacement from the centre of the polyhedron in the direction of the uncoordinated nitrate anion. The crystal structure displays numerous N-H center dot center dot center dot O hydrogen bonds.
引用
收藏
页码：M2893 / U364
页数：10
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