On the water promoted reaction of titanium isopropoxide with carbon dioxide

被引:20
|
作者
Ghosh, R [1 ]
Nethaji, M [1 ]
Samuelson, AG [1 ]
机构
[1] Indian Inst Sci, Dept Inorgan & Phys Chem, Bangalore 560012, Karnataka, India
关键词
D O I
10.1039/b307217g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Insertion of carbon dioxide into titanium isopropoxide takes place only in the presence of trace quantities of water to give an isopropyl carbonato cluster which has been crystallographically characterised.
引用
收藏
页码:2556 / 2557
页数:2
相关论文
共 50 条
  • [1] Catalytic metathesis of carbon dioxide with heterocumulenes mediated by titanium isopropoxide
    Ghosh, R
    Samuelson, AG
    CHEMICAL COMMUNICATIONS, 2005, (15) : 2017 - 2019
  • [2] Surface Reaction Kinetics of Titanium Isopropoxide and Water in Atomic Layer Deposition
    Reinke, Michael
    Kuzminykh, Yury
    Hoffmann, Patrik
    JOURNAL OF PHYSICAL CHEMISTRY C, 2016, 120 (08): : 4337 - 4344
  • [3] Synthesis of nanostructured titania powders via hydrolysis of titanium isopropoxide in supercritical carbon dioxide
    Stallings, WE
    Lamb, HH
    LANGMUIR, 2003, 19 (07) : 2989 - 2994
  • [4] Photodegradation of sulfamethoxazole promoted by titanium dioxide: Determination of reaction products
    Flanders, Phillip
    Hu, Lanhua
    Strathmann, Timothy J.
    Miller, Penney L.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2006, 231
  • [5] The Preparation of Titanium Dioxide Gas Sensors by the Electric Field Assisted Aerosol CVD Reaction of Titanium Isopropoxide in Toluene
    Panjawi, Naitik
    Naik, Anupriya
    Warwick, Michael E. A.
    Hyett, Geoffrey
    Binions, Russell
    CHEMICAL VAPOR DEPOSITION, 2012, 18 (4-6) : 102 - 106
  • [6] Sol formation rates in acid catalyzed titanium isopropoxide water reaction in isopropanol
    Wu, KT
    Spencer, HG
    JOURNAL OF NON-CRYSTALLINE SOLIDS, 1998, 226 (03) : 249 - 255
  • [7] REACTION OF TITANIUM POLONIDES WITH CARBON-DIOXIDE
    ABAKUMOV, AS
    MALYSHEV, ML
    REZNIKOVA, NF
    SOVIET RADIOCHEMISTRY, 1986, 28 (05): : 517 - 520
  • [8] Reaction mechanism studies on titanium isopropoxide-water atomic layer deposition process
    Rahtu, A
    Ritala, M
    CHEMICAL VAPOR DEPOSITION, 2002, 8 (01) : 21 - 28
  • [9] Use of chiral enolsilanes and chiral aldehydes in a Mukaiyama-type aldol reaction promoted by titanium(IV)isopropoxide
    Delas, C
    Blacque, O
    Moïse, C
    TETRAHEDRON LETTERS, 2000, 41 (43) : 8269 - 8272
  • [10] Reaction mechanism studies on titanium isopropoxide-water atomic layer deposition process
    Rahtu, Antti
    Ritala, Mikko
    Advanced Materials, 2002, 14 (02) : 21 - 28