Third-order perturbation theory for van der Waals interaction coefficients

被引:6
|
作者
Tang, Li-Yan [1 ]
Yan, Zong-Chao [2 ,3 ,4 ]
Shi, Ting-Yun [1 ]
Mitroy, J. [5 ]
机构
[1] Chinese Acad Sci, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan Inst Phys & Math, Wuhan 430071, Peoples R China
[2] Chinese Acad Sci, Ctr Cold Atom Phys, Wuhan 430071, Peoples R China
[3] Wuhan Univ, Dept Phys, Wuhan 430072, Peoples R China
[4] Univ New Brunswick, Dept Phys, Fredericton, NB E3B 5A3, Canada
[5] Charles Darwin Univ, Sch Engn, Darwin, NT 0909, Australia
来源
PHYSICAL REVIEW A | 2011年 / 84卷 / 05期
基金
加拿大自然科学与工程研究理事会; 澳大利亚研究理事会;
关键词
CORE POLARIZATION CORRECTIONS; DISPERSION COEFFICIENTS; PHOTOASSOCIATION SPECTROSCOPY; OSCILLATOR-STRENGTHS; HIGH-PRECISION; RANGE; STATE; POTENTIALS; MOLECULES; ENERGIES;
D O I
10.1103/PhysRevA.84.052502
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
The third-order expression for the dispersion interaction between two atoms is written as a sum over lists of transition matrix elements. Particular attention is given to the C-9/R-9 interaction which occurs in the homonuclear case when one atom is in an S state and the other is in a P state. Numerical values of the C-9 coefficient are given for the homonuclear alkali-metal dimers. The size of the C-9:C-3 dispersion coefficient ratio increases for the heavier alkali-metal atoms. The C-11 and C-13 coefficients between two helium atoms and lithium atoms in their ground states are also given.
引用
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页数:9
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